Please use this identifier to cite or link to this item: http://dspace2020.uniten.edu.my:8080/handle/123456789/9838
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dc.contributor.authorSaleh, M.I.
dc.contributor.authorSalhin, A.
dc.contributor.authorSaad, B.
dc.contributor.authorZain, S.M.
dc.contributor.authorRahman, N.A.
dc.contributor.authorArifin, Z.
dc.date.accessioned2018-03-06T03:50:22Z-
dc.date.available2018-03-06T03:50:22Z-
dc.date.issued1998
dc.identifier.urihttp://dspace.uniten.edu.my/jspui/handle/123456789/9838-
dc.description.abstractThe structure of the complex salt, [C26H40N2O4][Nd(NO3)5(H2O)] (1), was determined by single crystal X-ray diffraction. It consists of alternating layers of the anionic complex, [Nd(NO3)5(H2O)]2-, and the cationic diprotonated [2H.azacrown]2+. The Nd3+ complex anion is coordinated to five bidentate nitrate ligands and a water ligand to give an 11-coordinated environment. Each Nd moiety is linked to another through intermolecular hydrogen bonding to form pairs of Nd moieties. The azacrown adopts a chair conformation and the benzyl groups are attached to the nitrogen atoms in an anti position with respect to each other, above and below the plane of the macro-ring in agreement with the conformation of the uncomplexed protonated azacrown as obtained by the PM3 method.
dc.titleA structural study of the interaction of dibenzyldiaza-18-crown-6 with neodymium(III) nitrate hexahydrate
item.grantfulltextnone-
item.fulltextNo Fulltext-
crisitem.author.deptUniversiti Tenaga Nasional-
Appears in Collections:COE Scholarly Publication
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